Question bank/JEE Main/Chemistry

JEE MainChemistryModeratePhysical Chemistry

Inversion of sucrose (C12H22O11) is first-order reaction and is
studied by measuring angle of rotation at different instant of time

[IMAGE] If
(r∞−r0)=a\left( r_{\infty} - r_{0} \right) = a and
(r∞−rt)=(a−x)\left( r_{\infty} - r_{t} \right) = (a - x) (where r0r_{0}, rtr_{t}
and
r∞r_{\infty}are the angle of rotation at the start, at the time t
and at the end of the reaction respectively, then there is 50 inversion

when

Show answer and solution
Given,
(r∞−r0)=a,(r∞−rt)=(a−x)\left( r_{\infty} - r_{0} \right) = a,\left( r_{\infty} - r_{t} \right) = (a - x)
At 50 Inversion

a2=(a−x)\frac{a}{2} = (a - x)
(r∞−r0)2=(r∞−rt)\frac{\left( r_{\infty} - r_{0} \right)}{2} = \left( r_{\infty} - r_{t} \right)
(r∞−r0)=2r∞−2rt\left( r_{\infty} - r_{0} \right) = 2r_{\infty} - 2r_{t}
r0=2rt−r∞r_{0} = 2r_{t} - r_{\infty}

Source: Grass-G / CH-23 Chemistry Paper 31 Dec. FST.docx

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