Chemistry · Class 9-10 · CBSE

Metals, Non-Metals and the Reactivity Series

Explore physical and chemical properties of metals vs non-metals, the metal reactivity series, ionic bond formation in NaCl and MgCl2, properties of electrovalent compounds, and basic metallurgical processes.

1Physical and Chemical Properties Comparison

Elements are broadly classified intoMetals(electropositive elements that lose electrons to form cations) andNon-Metals(electronegative elements that gain electrons to form anions).

Metals vs Non-Metals: Physical Properties & Exceptions

  • Physical State

    Metals
    Solids at room temperature
    Non-Metals
    Solids and gases
    Important Exceptions
    Mercury (Hg) is liquid metal; Bromine (Br₂) is liquid non-metal
  • Malleability & Ductility

    Metals
    Highly malleable (beaten into foils) & ductile (drawn to wires)
    Non-Metals
    Brittle (shatter when hammered)
    Important Exceptions
    Gold & silver are most malleable/ductile; Zinc is brittle
  • Electrical Conductivity

    Metals
    Good conductors (free sea of electrons)
    Non-Metals
    Poor conductors / insulators
    Important Exceptions
    Graphite (carbon allotrope) is an excellent conductor of electricity
  • Hardness & Melting Point

    Metals
    Generally hard with high melting points
    Non-Metals
    Soft with low melting points
    Important Exceptions
    Sodium, Potassium are soft metals cut with knife; Diamond is hardest natural substance
  • Lustre

    Metals
    Metallic shine (lustrous)
    Non-Metals
    Dull appearance
    Important Exceptions
    Iodine (I₂) is a lustrous non-metal

2Reactivity Series and Chemical Reactions

The Reactivity (Activity) Series of Metals

  • Potassium & Sodium

    Chemical Symbol
    K, Na
    Reaction with Cold Water
    Violent reaction releasing H₂ gas that catches fire immediately
    Reaction with Dilute Acids
    Extremely explosive reaction
  • Calcium & Magnesium

    Chemical Symbol
    Ca, Mg
    Reaction with Cold Water
    Ca reacts with cold water; Mg reacts with hot water/steam
    Reaction with Dilute Acids
    Rapid evolution of H₂ gas
  • Aluminium, Zinc, Iron

    Chemical Symbol
    Al, Zn, Fe
    Reaction with Cold Water
    Do not react with cold/hot water; react with steam only
    Reaction with Dilute Acids
    Moderate evolution of H₂ gas
  • Lead, Hydrogen, Copper

    Chemical Symbol
    Pb, H, Cu
    Reaction with Cold Water
    No reaction with water or steam
    Reaction with Dilute Acids
    No reaction with dilute HCl / H₂SO₄
  • Silver & Gold

    Chemical Symbol
    Ag, Au
    Reaction with Cold Water
    Completely unreactive with water or steam
    Reaction with Dilute Acids
    Completely inert (dissolve only in Aqua Regia)

Formation of Ionic Bond in Sodium Chloride (NaCl)

  1. 1

    1. Sodium atom: Na (2, 8, 1) loses 1 valence electron to attain stable neon octet: Na → Na⁺ + e⁻.

  2. 2

    2. Chlorine atom: Cl (2, 8, 7) gains 1 electron to attain stable argon octet: Cl + e⁻ → Cl⁻.

  3. 3

    3. Strong electrostatic electrostatic forces of attraction bind oppositely charged Na⁺ and Cl⁻ into an ionic lattice.

  4. 4

    4. Result: Formation of solid crystalline Sodium Chloride (NaCl).

3Properties of Ionic Compounds and Metallurgy

General Characteristics of Ionic (Electrovalent) Compounds

  • Physical Nature

    Observed Property
    Hard and brittle crystalline solids
    Underlying Molecular Reason
    Strong electrostatic forces of attraction between positive and negative ions
  • Melting & Boiling Points

    Observed Property
    Very high (NaCl MP = 801°C)
    Underlying Molecular Reason
    Tremendous amount of thermal energy required to break rigid ionic lattice
  • Solubility

    Observed Property
    Soluble in polar solvents (water); insoluble in organic solvents (petrol/kerosene)
    Underlying Molecular Reason
    Water molecules hydrate and pull ions apart; nonpolar solvents cannot
  • Electrical Conduction

    Observed Property
    Conducts electricity in molten state or aqueous solution; NEVER in solid state
    Underlying Molecular Reason
    In solid state, ions are locked in fixed lattice; in liquid/aqueous state, ions are free to drift towards electrodes

4Exam Corner: Tips, Mistakes & Board Questions

Must-Know Metallurgical Terms for Exams

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Exam question · CBSE Class 10 Board

Why do ionic compounds not conduct electricity in solid state, but conduct in molten or aqueous state?
  1. A.Because electrons are absent in solids
  2. B.Because in solid state ions are tightly bound in fixed positions; in liquid/aqueous state ions become free to move
  3. C.Because solids are insulators
  4. D.Because ionic compounds undergo covalent bonding in water

Remember

  • Metals are electropositive (lose electrons); Non-metals are electronegative (gain electrons).
  • TheReactivity Seriesranks metals: K > Na > Ca > Mg > Al > Zn > Fe > Pb > H > Cu > Ag > Au.
  • Ionic compounds havehigh melting pointsand conduct electricity inmolten or dissolvedstate.
  • Roastingheats sulphide ores in air;Calcinationheats carbonate ores without air.

Check yourself

  1. Question 1

    Which of the following metals is protected from corrosion by an unreactive self-healing oxide layer?

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