Kinetic Theory

JEE Main level, single correct, medium

82 of 168

Question 82 of 168

Which statements are correct about degrees of freedom?
A. A molecule with
nn degrees of freedom has n2{n}^{2} different ways of storing energy.
B. Each degree of freedom is associated with
12RT\dfrac{1}{2}RT average energy per mole.
C. A monoatomic gas molecule has
11 rotational degree of freedom where as diatomic molecule has 22 rotational degrees of freedom
D.
CH4{CH}_{4} has a total to 66 degrees of freedom.
Choose the correct answer from the option given below:

Show answer and solution

Answer: (B) BB and DD only

According to the equipartition of energy, each degree of freedom carries 12RT\dfrac{1}{2}RT energy per mole and total energy per mole of a gas having nn degrees of freedom is 12nRT\dfrac{1}{2}nRT. Therefore, statement A is wrong and statement B is correct.
A monoatomic molecule only has translational degrees of freedom and does not have rotational degree of freedom. For a polyatomic model there are three rotational degrees of freedom and three translational degrees of freedom. Therefore, statement C is incorrect and statement D is correct.

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